diff --git a/doc/whatsnew/2/2.14/full.rst b/doc/whatsnew/2/2.14/full.rst
index 8790973589..4df9901e1d 100644
--- a/doc/whatsnew/2/2.14/full.rst
+++ b/doc/whatsnew/2/2.14/full.rst
@@ -90,6 +90,11 @@ Release date: 2022-06-01
 
   Refs #6462
 
+* Fixed a false positive regression in 2.13 for ``used-before-assignment`` where it is safe to rely
+  on a name defined only in an ``except`` block because the ``else`` block returned.
+
+  Closes #6790
+
 * Removed the ``assign-to-new-keyword`` message as there are no new keywords in the supported Python
   versions any longer.
 
diff --git a/pylint/checkers/variables.py b/pylint/checkers/variables.py
index 59d2fa0307..79c6fbac3b 100644
--- a/pylint/checkers/variables.py
+++ b/pylint/checkers/variables.py
@@ -680,12 +680,16 @@ def _uncertain_nodes_in_except_blocks(
             if closest_except_handler.parent_of(node):
                 continue
             closest_try_except: nodes.TryExcept = closest_except_handler.parent
+            # If the try or else blocks return, assume the except blocks execute.
             try_block_returns = any(
                 isinstance(try_statement, nodes.Return)
                 for try_statement in closest_try_except.body
             )
-            # If the try block returns, assume the except blocks execute.
-            if try_block_returns:
+            else_block_returns = any(
+                isinstance(else_statement, nodes.Return)
+                for else_statement in closest_try_except.orelse
+            )
+            if try_block_returns or else_block_returns:
                 # Exception: if this node is in the final block of the other_node_statement,
                 # it will execute before returning. Assume the except statements are uncertain.
                 if (
@@ -694,6 +698,13 @@ def _uncertain_nodes_in_except_blocks(
                     and closest_try_except.parent.parent_of(node_statement)
                 ):
                     uncertain_nodes.append(other_node)
+                # Or the node_statement is in the else block of the relevant TryExcept
+                elif (
+                    isinstance(node_statement.parent, nodes.TryExcept)
+                    and node_statement in node_statement.parent.orelse
+                    and closest_try_except.parent.parent_of(node_statement)
+                ):
+                    uncertain_nodes.append(other_node)
                 # Assume the except blocks execute, so long as each handler
                 # defines the name, raises, or returns.
                 elif all(
diff --git a/tests/functional/u/used/used_before_assignment_else_return.py b/tests/functional/u/used/used_before_assignment_else_return.py
new file mode 100644
index 0000000000..a5dc5c23b5
--- /dev/null
+++ b/tests/functional/u/used/used_before_assignment_else_return.py
@@ -0,0 +1,61 @@
+"""If the else block returns, it is generally safe to rely on assignments in the except."""
+
+
+def valid():
+    """https://github.com/PyCQA/pylint/issues/6790"""
+    try:
+        pass
+    except ValueError:
+        error = True
+    else:
+        return
+
+    print(error)
+
+
+def invalid():
+    """The finally will execute before the else returns."""
+    try:
+        pass
+    except ValueError:
+        error = None
+    else:
+        return
+    finally:
+        print(error)  # [used-before-assignment]
+
+
+def invalid_2():
+    """The else does not return in every branch."""
+    try:
+        pass
+    except ValueError:
+        error = None
+    else:
+        if range(0):
+            return
+    finally:
+        print(error)  # [used-before-assignment]
+
+
+def invalid_3():
+    """Not every except defines the name."""
+    try:
+        pass
+    except ValueError:
+        error = None
+    except KeyError:
+        pass
+    finally:
+        print(error)  # [used-before-assignment]
+
+
+def invalid_4():
+    """Should not rely on the name in the else even if it returns."""
+    try:
+        pass
+    except ValueError:
+        error = True
+    else:
+        print(error)  # [used-before-assignment]
+        return
diff --git a/tests/functional/u/used/used_before_assignment_else_return.txt b/tests/functional/u/used/used_before_assignment_else_return.txt
new file mode 100644
index 0000000000..d7d1835f49
--- /dev/null
+++ b/tests/functional/u/used/used_before_assignment_else_return.txt
@@ -0,0 +1,4 @@
+used-before-assignment:25:14:25:19:invalid:Using variable 'error' before assignment:CONTROL_FLOW
+used-before-assignment:38:14:38:19:invalid_2:Using variable 'error' before assignment:CONTROL_FLOW
+used-before-assignment:50:14:50:19:invalid_3:Using variable 'error' before assignment:CONTROL_FLOW
+used-before-assignment:60:14:60:19:invalid_4:Using variable 'error' before assignment:CONTROL_FLOW